Description succincte
(Anglais)
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In a third generation approach weak intra- and intermolecular forces of the secondary coordination sphere are applied in tuning efforts of organometallic homogeneous catalyses. Based on hydrogen bonding, weak ionic and coordinative forces and v.d. Waals (non-covalent) forces reactive intermediates and transition states of crucial catalytic elementary reactions are optimized with respect to their specific chemical tasks to achieve higher selectivities and activities of the catalyses. Sophisticated MS techniques and DFT methodologies will be used to identify and quantify reactive intermediates and transition states.
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Partenaires et organisations internationales
(Anglais)
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AT, BE, CH, CZ, DE, DK, ES, FI, FR, GR, HR, HU, IL, IT, LT, NL, NO, PL, PT, SE, SI, UK
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Résumé des résultats (Abstract)
(Anglais)
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In a third generation approach weak intra- and intermolecular forces of the secondary coordination sphere are applied in tuning efforts of organometallic homogeneous catalyses. Based on hydrogen bonding, weak ionic and coordinative forces and v.d. Waals (non-covalent) forces reactive intermediates and transition states of crucial catalytic elementary reactions are optimized with respect to their specific chemical tasks to achieve higher selectivities and activities of the catalyses. Sophisticated MS techniques and DFT methodologies were used to identify and quantify reactive intermediates and transition states of metal-included and metal-free reactions.
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