Abstract
(Englisch)
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The research of the proposed network is aimed at the study of the supermolecular organization in amphiphilic macromolecular systems of complex architectures. In particular, our efforts will focus on the study the hierarchical self-assembly of amphiphilic macromolecules differing in their molecular architecture, driven by multiple types of interactions, both in aqueous solution and at interfaces. The spectrum of molecular architectures will range from simple linear structures over branched structures and more complex nanoparticles. We aim to understand how self-organization, the resulting structures and interfacial patterns are controlled by the interplay of macromolecular architecture of building blocks with different types and ranges of competing interactions, particularly hydrophobic and electrostatic interactions. We aim at the design of highly responsive systems capable for switching of the aggregation state and supermolecular organization upon variation of the external conditions. Our ultimate goal is to create and understand systems that can hierarchically self-assemble. The present project aims at exploring possible approaches and should be seen as the first step in this challenging direction. The strongly complementary expertise of the participating groups (synthesis, characterization, modelling, applications) and their co-ordinated efforts will guarantee the success of the proposed interdisciplinary research by bringing us to a qualitatively new level of understanding of self-organization of amphiphilic macromolecular systems. This network, spanning six countries with 13 teams, is aimed to provide excellent training for early-stage researchers in an inspiring, interdisciplinary, multi-national academic and industrial environment. The scientific experience, complemented by a training in complementary skills (language, presentation, communication, management, ...) will enable them to an excellent standing on the European job market and in European academia.
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