Novel Phosphorus Acid Chiral Di-nuclear Ru-Complexes Derived from Binap and MeO-Biphep. Synthesis and Diffusion Studies

• Unité de recherche: COST
• Numéro de projet: C03.0003
• Titre du projet anglais: Novel Phosphorus Acid Chiral Di-nuclear Ru-Complexes Derived from Binap and MeO-Biphep. Synthesis and Diffusion Studies

Mots-clé (Anglais)

Chiral dinuclear ruthenium complexes; diffusion measurements

Programme de recherche (Anglais)

COST-Action D24 - Sustainable Chemical Processes: Stereoselective Transition Metal-Catalysed Reactions

Description succincte (Anglais)

Synthisis of a new class of chiral dinuclear ruthenium complexes will be undertaken. These new materials (which will be characterized partially via diffusion measurements) will be tested as potential reagents for resolving racemic alkohols and amines.

Partenaires et organisations internationales (Anglais)

AT, BE, DK, FI, FR, DE, EL, HU, IE, IT, LV, MT, NL, NO, PL, PT, RO, SI, ES, SE, CH, UK

Résumé des résultats (Abstract) (Anglais)

New Ruthenium (IV catalysts have been prepared and used in the regioselective homogeneous, allylic alkylation, amination and phenolation reactions. The source of the observed regioselectivity has been explained using DFT, NMR abd X-ray studies. A new catalysed Friedel-Crafts reaction has been discovered.

Références bases de données (Anglais)

Swiss Database: COST-DB of the State Secretariat for Education and Research Hallwylstrasse 4 CH-3003 Berne, Switzerland Tel. [phone] Swiss Project-Number: C03.0003