ServicenavigationHauptnavigationTrailKarteikarten

Research unit
COST
Project number
C03.0003
Project title
Novel Phosphorus Acid Chiral Di-nuclear Ru-Complexes Derived from Binap and MeO-Biphep. Synthesis and Diffusion Studies

Texts for this project
 GermanFrenchItalianEnglish
Key words
-
-
-
Anzeigen
Research programs
-
-
-
Anzeigen
Short description
-
-
-
Anzeigen
Partners and International Organizations
-
-
-
Anzeigen
Abstract
-
-
-
Anzeigen
References in databases
-
-
-
Anzeigen

Inserted texts


CategoryText
Key words
(English)
Chiral dinuclear ruthenium complexes; diffusion measurements
Research programs
(English)
COST-Action D24 - Sustainable Chemical Processes: Stereoselective Transition Metal-Catalysed Reactions
Short description
(English)
Synthisis of a new class of chiral dinuclear ruthenium complexes will be undertaken. These new materials (which will be characterized partially via diffusion measurements) will be tested as potential reagents for resolving racemic alkohols and amines.
Partners and International Organizations
(English)
AT, BE, DK, FI, FR, DE, EL, HU, IE, IT, LV, MT, NL, NO, PL, PT, RO, SI, ES, SE, CH, UK
Abstract
(English)
New Ruthenium (IV catalysts have been prepared and used in the regioselective homogeneous, allylic alkylation, amination and phenolation reactions. The source of the observed regioselectivity has been explained using DFT, NMR abd X-ray studies. A new catalysed Friedel-Crafts reaction has been discovered.
References in databases
(English)
Swiss Database: COST-DB of the State Secretariat for Education and Research Hallwylstrasse 4 CH-3003 Berne, Switzerland Tel. +41 31 322 74 82 Swiss Project-Number: C03.0003