P-C Bond Splitting Reactions in Ru(II) Complexes of MeO-Biphep Using CF3SO3H and HBF4. A Novel Ru - F - H Interaction

• Unité de recherche: COST
• Numéro de projet: C00.0024
• Titre du projet anglais: P-C Bond Splitting Reactions in Ru(II) Complexes of MeO-Biphep Using CF3SO3H and HBF4. A Novel Ru - F - H Interaction

Mots-clé (Anglais)

RU-organometallics; novel binding; P-C bond splitting

Programme de recherche (Anglais)

COST-Action D12 - Organic Transformations: Selective processes and Asymmetric Catalysis

Description succincte (Anglais)

See abstract

Partenaires et organisations internationales (Anglais)

A, B, HR, CZ, DK, F, D, H, IRL, I, LV, NL, N, PL, P, RO, SI, E, S, CH, GB

Résumé des résultats (Abstract) (Anglais)

A series of unexpected new chiral organometallic Ru-complexes have been prepared starting from Ru(II) Binap and Ru(II) MeO-Biphep phosphine compounds. The new complexes, which arise from stereospecific P-C bond making reactions, demonstrate unusual and in some cases unprecedented olefin-ruthenium binding modes. The mechanistic knowledge gained during this chemistry has allowed a facile synthesis of new chiral ruthenium hydride arene complexes to be developed.

Références bases de données (Anglais)

Swiss Database: COST-DB of the State Secretariat for Education and Research Hallwylstrasse 4 CH-3003 Berne, Switzerland Tel. [phone] Swiss Project-Number: C00.0024